Food safety and botulism indicators for pressure canned goods

The layer on the top is either separated fat from the ham and bouillon cubes, or a bacterial and/or fungal growth (aka a "pellicle"). If it feels greasy and/or brittle and becomes transparent when heated, it was just fat. If it feels rubbery and maintains its coherence when heated, it was a pellicle. A pellicle is not an indication of a botulinum infection, but it's definitely an indication that you screwed up the canning process and that the contents are inedible.

There is no way for a home cook to determine if a can of food is safe to eat. That would require special expertise and lab work (including, when testing for botulism, injecting mice with the stuff). Instead, what you do is use a trustworthy recipe, make sure you're following the recipe properly (with a canner that reaches the appropriate pressure for the appropriate amount of time), and check that the vacuum seal has not been compromised before eating. That is, rather than seeing whether the food is safe, you ensure that your process guarantees safe food.

The steps you posted are horrible -- neither safe, nor effective, and betraying a fundamental misunderstanding of what botulism even is -- and you should no longer trust whoever wrote them. "Have a bite and wait a day"? Cripes on a cracker.