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Understanding time crystals

Physics Asked by user929304 on July 26, 2021

In very recent publications, two groups in Maryland (paper: “Observation of a Discrete Time Crystal”) and Harvard (paper: “Observation of discrete time-crystalline order in a disordered dipolar many-body system”) have separately worked on constructing time crystals following the path paved by the previous works of Norman Yao (e.g. “Discrete time crystals: rigidity, criticality, and realizations” ). For example Chris Monroe et al. (Maryland) have realised (or claim to have) a time crystal by entangling the electron spins of a set of ytterbium ions while keeping the system out of equilibrium by alternately hitting the ions by a laser (to apparently create an effective magnetic field) and by another laser to flip their spins, in a repetitive manner.

Now time crystals have been previously theoretically predicted to exist “Classical Time Crystals” and “Quantum Time Crystals”, representing an out-of-equilibrium form of matter, in contrast to the commonly well known equilibrium forms of matter (solid, gas, liquids, liquid crystals…). So it is really great to see such works emerging and the field gaining steam on an experimental level.

That said, admittedly, it is very difficult to grasp these works for someone not involved in the field, but it would be incredibly valuable if, briefly, just the idea of time crystals could be explained at a conceptual level.
As in, what qualifies them as a new form of matter? Surely this form is dependent on some external drive to be kept out of equilibrium, right?

Which then begs to ask “how can it be a naturally occurring form of matter”. On the other hand, what does it have in common with the usual concept of crystals, whose whole structure can be represented by spatially replicating the unit cell.
Is the time crystal an addendum to the latter by extending its spatial symmetry to also include a time symmetry?

This is merely an attempt to get more input in order to understand some of the main ideas involved in the original works of Frank Wilczek and Norman Yao. These new experimental realizations (see first paragraph) are very exciting to find out about.

One Answer

The key idea is that time crystals are externally driven at a certain frequency, but they respond at a different (in fact, slower) frequency.

First of all, terminology:

what does it have in common with the usual concept of crystals, whose whole structure can be represented by spatially replicating the unit cell. Is the time crystal an addendum to the latter by extending its spatial symmetry to also include a time symmetry?

Sort of, but it's more than that. The key property of a crystal that they're generalizing is not just that it's periodic in space, but that it's spontaneously spatially periodic. In other words, you can start with a bunch of randomly arranged atoms whose interactions are perfectly translationally invariant, and they "fall into" a crystalline lattice on their own - you don't manually need to assemble the solid by adding in one atom at a time with atomic-spacing precision.

As an extremely rough analogy, let's imagine that you tried manually "packing" atoms into a lattice by subjecting them to a spatially periodic external potential. One could imagine that if the atoms are strongly repulsive, then the external potential won't be strong enough to pack them into adjacent lattice sites, so instead they will occupy every other site in the external potential. And of course, which set of "every other site" - the even- or odd-numbered sites - is randomly and unpredictably (or "spontaneously") selected.

Similarly, you could imagine a time crystal that you're weakly driving once per second, but it's so disordered that it keeps getting "semi-stuck" in its current configuration and can't keep up with the drive, so it only flops around once every two seconds. (The atoms in the previous analogy correspond to changes in the time crystal's state, and the repulsion between the atoms in the analogy corresponds to the system not "wanting" to frequently change its state.) This may not sound incredibly exotic, but it turns out that no one's ever discovered a material that does this, and up until recently it was thought to be impossible on theoretical grounds (namely Floquet's theorem), until some very clever people thought of some loopholes. "Time crystal" is kind of a silly name, but that's what stuck.

You are correct that because time crystals inherently depend on an external drive (at least, we think they do), you can't use equilibrium stat mech and you have to adopt a slightly different definition of a "state of matter" - in this case, the property of the material response spontaneously doubling (or tripling, etc.) the period of the external drive. Also, as you say, you're unlikely to find a time crystal in nature, if by "nature" you mean "a cave in Utah." But they may not be quite as exotic as you think. For example, simply shining a classical light wave of fixed frequency can drive a solid via the AC Stark effect, so you wouldn't necessarily to do anything to fancy to get the external drive.

Edit: people usually use the word "crystal" to mean a spatially periodic structure, but that's not the sense of the word being used in the phrase "time crystal." The key point of a crystal that's being generalized is that it spontaneously breaks translational symmetry, because the Hamiltonian has a certain translational symmetry, but any ground state has less translational symmetry. For a regular spatial crystal, the individual atoms' interactions have continuous translational symmetry - if you move every atom in the same direction by an arbitrarily small amount, the energy doesn't change. But if the interactions are such that the ground state forms a crystal structure, then that crystal only has discrete translational symmetry - the crystal looks the same if you translate it by one lattice constant, but not if you translate it by a fraction of a lattice constant. The ground state still has some "residual" translational symmetry left over from the original Hamiltonian, but it's less symmetry than before, because there are fewer translation operations (by integer numbers of lattice spacings) that leave the crystal invariant than translation operations (by any amount) that leave the original Hamiltonian invariant. Mathematically, we say that the original symmetry group $mathbb{R}$ gets spontaneously broken down to the proper subgroup $mathbb{Z}$.

In my "repulsive atom" analogy above, the Hamiltonian has discrete translational invariance with a lattice constant set by the periodic external potential. But if the atoms repel and only fill up every second (third, etc.) site of the lattice, then the physical ground state is still spatially periodic, but with a period twice (three times, etc.) the period set by the external potential. We say that "the unit cell has spontaneously doubled," because the ground state still has some translational symmetry, but less than before (translation by an even number of original lattice spacings is still a symmetry, but translation by an odd number no longer is).

Similarly, a time crystal simultaneously doubles (or triples, etc.) the "unit cell" of time translation. If the Hamiltonian is periodic in time with period $T$, but the physical crystal's time evolution is periodic with period $2T$ ($3T$, etc.) then it "spontaneously breaks" the Hamiltonian's time translational symmetry (by any integer multiple of $T$) down to a smaller set of symmetry operations - those consisting of an integer multiple of the new period $2T$, or equivalently an even multiple of $T$. Just as the effective lattice constant doubled in our atom analogy, the "time translational unit cell" doubles from $T$ to $2T$ in our time crystal.

(Technical detail: the Hamiltonian for a time crystal is disordered in space, but perfectly periodic in time - so the time translational invariance that gets spontaneously broken is indeed a perfect symmetry of the Hamiltonian. The spatial disorder is needed in practice for rather technical reasons, but is completely unimportant conceptually.)

Correct answer by tparker on July 26, 2021

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