Physics Asked on March 30, 2021
Some pieces of literature derives Joule thompson coefficent using enthalpy $H$ and others derive it using internal energy $U$ … so which one is the right one? If they are both equivalent, then how do you prove their equivalence?
Edit: Ok, I realized there are actually two different JT coefficents called the JT coefficent. So, I seek an answer which discusses both.
Sources which derive using internal energy:
Lecture -3 of mit ocw around 49:14
Page-63 of Atkin’s physical chemistry (internal edition)
Robert G. Mortimer – Physical Chemistry (page -63) for experimental explanation of this phenomena
Sources which derive using enthalpy:
Joule thompson coefficent in wiki
Charles Kittel, Herbert Kroemer – Thermal physics-W. H. Freeman [ page 362, chapter-12 cryogenics]
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