Physics Asked by Physics Student on April 6, 2021
The Feynman lectures volume 3 chapter 9 analyzes the ammonia molecule. It assumes there are only two base states. The amplitude, $C_1$, to be in the first state, $lvert1rangle$, in which the nitrogen atom is above the plane of the three hydrogen atoms is given by,
$$C_1=frac{a}{2}e^{-(i/hbar)(E_0-A)t}+frac{b}{2}e^{-(i/hbar)(E_0+A)t}.tag{9.2}$$
and the amplitude, $C_2$, for the nitrogen atom to be in the second base state, $lvert2rangle$, where the nitrogen atom is below this plane is,
$$C_2=frac{a}{2}e^{-(i/hbar)(E_0-A)t}-frac{b}{2}e^{-(i/hbar)(E_0+A)t}.tag{9.3}$$
There are two stationary states. The first one is $lvertpsi_Irangle$ and corresponds to when $a=0$ in $(9.2)$ and $(9.3)$. The other one is $lvertpsi_{II}rangle$ and corresponds to when $b=0$ in $(9.2)$ and $(9.3)$. The amplitude to be in the new base states $C_I$ and $C_{II}$ are given as,
$$C_I=frac{1}{sqrt2}[C_1-C_2], C_{II}=frac{1}{sqrt2}[C_1+C_2].tag{9.13}$$
Equation $(9.10)$ for the state $lvertpsi_Irangle$, also says these amplitudes should be,
$$C_I=e^{-(i/hbar)(E_0+A)t}, C_{II}=0.tag{9.10}$$
When I try to calculate $C_{II}$ for state $lvertpsi_Irangle$ for when $a=0$, I get,
$C_{II}=frac{1}{sqrt2}[C_1+C_2]=frac{1}{sqrt2}[frac{b}{2}e^{-(i/hbar)(E_0-A)t}-frac{b}{2}e^{-(i/hbar)(E_0-A)t}]=0$
which is the same $C_{II}$ as given in $(9.10)$, but when I try to calculate $C_{I}$ I get,
$C_I=frac{1}{sqrt2}[C_1-C_2]=frac{1}{sqrt2}[frac{b}{2}e^{-(i/hbar)(E_0-A)t}+frac{b}{2}e^{-(i/hbar)(E_0-A)t}]=frac{b}{sqrt2}e^{-(i/hbar)(E_0+A)t}$
This is exactly the same as $C_{I}$ in $(9.10)$ except for the factor $frac{b}{sqrt2}$. Are you able to just assume that $b=sqrt2$ to eliminate this factor and make $C_I$ equal to what is shown in $(9.10)$, or is this incorrect?
The constant $b$ can be solved as follows. Suppose that at $t=0$ we know the molecule is in state $lvert{I}rangle$, then $C_{I}(0)=1$. Now knowing that $a=0$
$C_I(0)=frac{1}{sqrt2}[C_1(0)-C_2(0)]=frac{1}{sqrt2}[frac{b}{2}e^{-(i/hbar)(E_0+A)(0)}+frac{b}{2}e^{-(i/hbar)(E_0+A)(0)}]=frac{b}{sqrt2}=1$
Therefore,
$b={sqrt2}$
Answered by Physics Student on April 6, 2021
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