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Enthalpy of formation of the oxygen molecule

Physics Asked on March 29, 2021

I want to obtain the enthalpy of formation of the oxygen molecule .From the wikipedia table of enthalpies of compound formation, we can obtain the following values ​​for carbon dioxide and carbon monoxide (for $T=25^circ C$):

Carbon dioxide:

  1. $Delta H_f^circ$ (kJ/mol)= -393.52
  2. J/mol=-393520

Carbon monoxide

  1. $Delta H_f^circ$ (kJ/mol)=-110.53

  2. J/mol=-110530

Are the above data sufficient to obtain the enthalpy of formation of the oxygen molecule?

One Answer

Not quite enough information. But the answer is simple, the heat of formation of each element is taken as zero. See probably any modern thermodynamics text. $Thermodynamics$ by W C Reynolds, (1965) on page 302 states "...by convention the elemental substances have zero enthalpy at the standard reference state..." So, $O_2$ is zero. From this you can find the heat generated by burning CO and half a mole of oxygen to carbon dioxide.

Correct answer by W H G on March 29, 2021

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