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Element well in periodic table

Physics Asked by Agnius Vasiliauskas on October 18, 2020

It may be a very stupid question, but still. Given a periodic table

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Why there is a well/hole of missing elements in atop of periodic table ?
(Pictured as green area). Is this just a side-effect of standard element distribution logic in a table ? Can something be put in these missing places, like different isotopes of elements ? I understand that last pair of rows needs to be put somewhere, because elements without a group are kind of "heretical". But just an empty space in a periodic table feels a bit weird, like some elements are missing or that some are "forbidden".

EDIT

BTW, interesting fact,- in that hole above there’s a $36$ empty element places in total and there are $28$ elements in total without a group assigned to them (last pair of rows). So these last two rows would fit perfectly in that hole above. Maybe it can mean that these last rows have some group in reality ? Or that periodic table may be re-structured more optimally.

One Answer

The periodic table is arranged in vertical columns called groups and horizontal rows called periods. As you have noticed, different rows contain different numbers of elements, and the the columns are arranged so that there are gaps in the middle of the rows. Why is this ?

The electrons that surround the atoms of each element are arranged into layers called shells. There is a fixed maximum number of electrons in each shell. The innermost shell can contain at most two electrons, which is why the first row only contains two elements, hydrogen (atomic number $1$) and helium (atomic number $2$). The maximum number of electrons in each shell increases as you go outwards from the nucleus, which is why the rows become longer as you move down the table - rows $2$ and $3$ contain $8$ elements each, and rows $4$ and $5$ contain $18$ elements each.

So why are there gaps in the rows ? Why not shuffle all the cells in each row to the left hand side, so that for example helium is above beryllium. After all, both of these elements contain two electrons in their outermost shell.

The columns are arranged so that elements with similar chemical behaviours line up in the same column. And it turns out that the most important single factor that determines the chemical behaviour of an element is not how many electrons are in the outermost shell, but how close the outermost shell of electrons is to being a complete shell.

Hydrogen has similar chemical behaviour to lithium and sodium because all of these elements have just one electron in their outermost shell. So we put hydrogen, lithium and sodium in the same group, which is the left hand column. But helium, with two electrons in its outermost shell, has similar chemical behaviour to neon and argon, with eight electrons in their outermost shells, because all of these elements have a full outermost shell. So we put helium, lithium and argon in the same group, which is the right hand column.

We are used to this "traditional" design for the periodic table, but it is not the only possible design. Various alternative designs have been proposed - see this Wikipedia article for a summary. In particular, French engineer Charles Janet proposed a "left-step" arrangement which avoids the gaps in the rows. In Janet's left-step arrangement, helium does sit immediately above beryllium.

Correct answer by gandalf61 on October 18, 2020

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