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Does molten potassium wet steel?

Physics Asked on July 29, 2021

I’m designing a device that uses molten potassium in steel pipes. If the device cools, the potassium will solidify and shrink, and if it’s adhered strongly to the pipes I’m worried they may crack, so I was wondering if potassium wets steel.

One Answer

The previous commenters are correct--potassium is exceedingly soft and should not pose a significant mechanical hazard to steel. Molten alkali metals are often used as coolant in nuclear reactors, where they are contained within steel components without any mechanical problems. Chemical safety, of course, should be your major concern with this design, as potassium will react violently with oxygen or water.

As an aside, the eutectic NaK alloy (about 79% potassium, 21% sodium) is actually liquid at room temperature; so this may eliminate the solidification problem altogether, unless you're dealing with cryogenic temperatures.

Answered by Brian Ensign on July 29, 2021

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