TransWikia.com

Do we have to treat ideal gas as identical particle?

Physics Asked by Harry Shieh on June 21, 2021

In Quantum Mechanics 2nd edition by Griffiths, he says we can get Maxwell-Boltzmann distribution as we deal with distinguishable particles. And I think ideal gas follows MB distribution; therefore, I think ideal gas is distinguishable until now.

However when I start learning thermal physics, the textbook tells me if a system has N gas, and for each gas it has Z (partition function) individually.
Then for the N-gas system, the partition function is $Z^n/n!$.
Because Gibbs treats it as identical.

So, the question is …
the ideal gas should be treat as identical or not??P

(Actually I have a thought experiment for this..p)

If we have 4 ideal gas particle in a room with volume 2V, and I separate the space as V+V virtually.
Evidently, we know each volume V could have 2 particle in average when it reach equilibrium.
And my reason is it has only 1 configuration when all particles are in the same V, but it has $$6=frac{4!}{2!2!}$$
When the gas are distributed equally in the 2V. it has the highest multiplicity, which we can infer it has the highest entropy.

However as I think like this, I’ve already treated it as distinguishable.

Add your own answers!

Ask a Question

Get help from others!

© 2024 TransWikia.com. All rights reserved. Sites we Love: PCI Database, UKBizDB, Menu Kuliner, Sharing RPP