Physics Asked on September 3, 2021
I’m confused on the difference in results I’m seeing for the density of states for a free electron (for example, a conduction electron in a metal). For one textbook (Kittel), I’m seeing that the density of states depends on the volume of the system, whereas in another, the density of states does not depend on the volume. I think this may be due to a differing definition of density of states but I can’t quite figure this out. My question is two-fold:
Below are derivations in two textbooks showing the derivation for the density states of a free electron confined to some volume V.
I think the difference here is that Kittel gives the number of states per unit energy, while Chenming is giving the number of states per unit energy per unit volume. Take Kittel's expression and divide through by the volume to get the same units as Chenming and one gets the following: $$frac{frac{dN}{depsilon}}{V}=frac{(2m)^{1.5}epsilon^{0.5}}{2pi^2hbar^3}=frac{(8pi^3)(2m)^{1.5}epsilon^{0.5}}{2pi^2 h^3}=frac{4pi(2m)^{1.5}epsilon^{0.5}}{h^3} = frac{8pi m(2mepsilon)^{0.5}}{h^3}$$ which is the same as Chenming's expression.
Correct answer by CGS on September 3, 2021
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