Physics Asked by Thor of University Mitguard on January 7, 2021

I am trying to derive an equation for chemical potential from Boltzmann entropy and this is what I have come up with so far:

$$S = kln{left(frac{N!}{N_mathrm{up}!,N_mathrm{down}!}right)} label{eq:1} tag{1}$$

and the derivation of chemical potential from the 1st law of thermodynamics,

$$mu = -Tleft(frac{partial S}{partial N}right)_{UV} tag{2}$$

I have used Stirling’s approximation and properties of logs and have come up with an answer, but after searching for my answer it is not online anywhere, so it feels like I might be going in the wrong direction.

From my computation of entropy which I found to be,

$$S = k_bleft( Ncdotln{N} – sum(N_icdotln{N_i}) right) tag{3}$$

I got chemical potential to be

$$mu = -Tk_bleft( ln{N} +1 – sum{(ln{N_i} + 1)} right) tag{4}$$

Is this a derivation for entropy that anyone has ever seen before? Is it even possible to take the equation $eqref{eq:1}$ and derive an equation for chemical potential?

Any answer or push in the right direction would be greatly appreciated.

Start with $$ S(N_1,N_2) = k logfrac{(N_1+N_2)!}{N_1! N_2!} $$ Write the chemical potential as begin{align} mu &= - kTleft(frac{partial S}{partial N_1}right)_{N_2} &= -kT frac{S(N_1+1,N_2)-S(N_1,N_2)}{(N_1+1)-N_1} & = -kT log frac{(N_1+N_2+1)!}{(N_1+N_2)!} frac{N_1!}{(N_1+1)!} frac{N_2!}{N_2!} & = -kT frac{N_1+N_2+1}{N_1+1} end{align} Make the approximation $$ frac{N_1+N_2+1}{N_1+1} approx frac{N_1+N_2}{N_1} = frac{1}{x_1} $$ and write the final result as $$ boxed{ vphantomint mu = kT log x_i } $$ with $$ x_i = frac{N_i}{N} = frac{N_i}{sum_i N_i} $$

Answered by Themis on January 7, 2021

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