Can we use both validation loss and cross validation at the on CNN?

Yes, you are right validation loss is used to show when an ML model is overfitting it's training data. However this only occurs when your training data doesn't fit your model, especially when it's quite low. cross validation is iterating your validation data over your training data because there is no sufficient data to account for both training, validation and test data. Thus its possible to used both of them to evaluate and improve your models performance although they are different concepts.