Chemistry Asked on October 5, 2021
I encountered a weird question in an exam. The statement says that instead of radical substitution, cyclopropane undergoes electrophilic addition reaction in sunlight.
I know that all saturated compounds give substitution reactions in sunlight but the answer key states that electrophilic addition takes place.
I couldn’t find any source to prove this. Any help with an explanation and a verified source would be appreciated.
It should say "in addition to" rather than "instead of".
Cyclopropane suffers badly from ring strain. The bond angles in the ring are 60° rather than the normal ~109.5° when carbon makes four single bonds. In the absence of light, when in contact with $Cl_2$ or $Br_2$ the ring will break and addition occur.
In sunlight, both the expected substitution reactions and the addition reaction will occur.
Can't find the reference I thought I remembered, but here's a site or two discussing it:
https://www.chemguide.co.uk/organicprops/alkanes/halogenation.html
Correct answer by Gwyn on October 5, 2021
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