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Why are reaction rates proportional to the the product of the reactants not their sum?

Physics Asked by M. Z. on April 25, 2021

For example, if we have the following Birth-Death process

Birth-Death reaction

Why is the differential equation describing this reaction given by

Equation describing reaction

Where x, y, and a are the number of the reactants (X, Y, and A respectively). The rate is always proportional to the product of the number of reactants, but why not their sum?

One Answer

Where x, y, and a are the number of the reactants (X, Y, and A respectively). The rate is always proportional to the product of the number of reactants, but why not their sum?concentration (or even better chemical acti

'number of the reactants' is an ambiguous term: concentration (or even better chemical activity) is more accurate.

If we take a simple reaction:

$$text{A}+text{B}to text{C}$$

Then in accordance with kinetic theory the rate of reaction is proportional to:

$$frac{text{d}[C]}{text{d}t}propto [A]$$ and: $$frac{text{d}[C]}{text{d}t}propto [B]$$

It follows that: $$frac{text{d}[C]}{text{d}t}propto [A]times [B]$$ And: $$frac{text{d}[C]}{text{d}t}=k [A][B]$$

Where the bracketed quantities are concentrations.

Correct answer by Gert on April 25, 2021

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