Physics Asked on December 21, 2020
I am reading this article The use of basis splines and non-orthogonal orbitals in R-matrix calculations: Application to Li photoionization
At some point they span a wave function $Psi_{E}$ in terms of energy independent basis
$Psi_{E}=sum_{k} A_{E k} Psi_{k}$
Here for example The Structures of Binary Compounds it is said that LCAO is a energy independent basis.
Here Bound states of a short-range potential
we have
To calculate the energy spectrum, we
write the energy eigenvalue equation (wave equation) $H|psirangle=E|psirangle$ in the energy independent basis as $sum_{m} f_{m} Hleft|phi_{m}rightrangle=E sum_{m} f_{m}left|phi_{m}rightrangle .$
so it seems that energy independent basis is basis whose vector has the same energy.
My question is what is a energy independent basis?
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