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Why HBr has stronger attraction between molecules than CH3NH2?

Chemistry Asked by Molly_K on October 5, 2021

Which of the following compounds exhibits dipole-dipole forces as its strongest attraction between molecules?

a) $ce{CO2}$
b) $ce{CH3NH2}$
c) $ce{Kr}$
d) $ce{H2}$
e) $ce{HBr}$

From what I understand, $ce{CH3NH2}$ has an H-bond and it’s the strongest form of dipole-dipole. So I thought that would be the answer.

I also knew that $ce{HBr}$ shows the greatest electronegativity difference between $ce{H}$ and $ce{Br}$ atom, it would be a polar covalent bond (?!).

In that case, $ce{HBr}$ may have stronger attraction between molecules than $ce{CH3NH2},$ but it is not dipole-dipole. Isn’t that correct? Then shouldn’t the answer be $ce{CH3NH2}$ instead of $ce{HBr}?$

I must have some concept issues here.

One Answer

EDIT (after title edited): $ce{HBr}$ doesn't have stronger interaction than $ce{CH2NH2}$, but it has dipole-dipole interaction as the strongest forces between it's molecules, which is obviously weaker than H-bonding.


Hydrogen bonding is the strongest intermolecular attraction. It is a type of dipole-dipole interaction1, but it is specific to Hydrogen.

In general, dipole-dipole interactions are considered weaker than H-bonding. The relative strength of forces are as follows,

Hydrogen bonding > Van der Waals dipole-dipole interactions > Van der Waals dispersion forces

As per your question, (a), (c) and (d) have dispersion forces (as they're non-polar), while (b) has H-bonding as it's strongest interaction (not dipole-dipole).

Finally, as only (e) has dipole-dipole as it's strongest attraction between molecules, hence it's the answer.


Notes:

1: Dipoles are created due to difference in electronegativity. Below image shows that there is sufficient electronegativity difference to create a dipole. H-bonding and dipole-dipole interactions have same origins.

enter image description here

![H-BONDING and dipole-dipole interactions](https://cdn.masterorganicchemistry.com/wp-content/uploads/2019/11/3-van-der-waals-dipole-dipole-interactions-acetone-methyl-acetate-propyl-fluoride.gif)

(Source: Master Organic Chemistry)

Correct answer by Rahul Verma on October 5, 2021

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